UN 0027
Dangerous Goods · Explosive substances and articles

BLACK POWDER (GUNPOWDER), granular or as a meal

Class 1

Modal carriage coverage

Full enriched detail — special provisions, packing, tank and equipment — is provided for ADR (road) only. Other modes show the listing summary (class, packing group, limits) from BAM.

Carriage modeConvention StatusClass Packing groupLimited quantities
Road ADR / Annex A Listed 1 0
Rail RID Listed 1 0
Inland waterway ADN Listed 1 0
Sea IMDG Code Listed 1.1D 0
Air ICAO TI / IATA DGR Listed 1.1D
ADR 2025 (UNECE) · RID / ADN / IMDG / ICAO listings via BAM

Multi-modal Table A

Each convention's own dangerous-goods-list columns, shown as published by BAM. Codes are not resolved to text — full enrichment is ADR-only. Verify against the official source.

IMDG · Table A

Class
1.1D
Limited quantities
0
Excepted quantities
E0
Packing instructions
P113
EmS
F-B, S-Y
Stowage category
04
Stowage & handling
SW1

RID · Table A

Class
1
Classification code
1.1D
Subsidiary risk
(13)
Limited quantities
0
Excepted quantities
E0
Packing instructions
P113
Transport category
1
Hazard ID number
1.1D

ADN · Table A

Class
1
Classification code
1.1D
Limited quantities
0
Excepted quantities
E0
Equipment required
PP
Blue cones / lights
3
Additional measures
LO01, HA01, HA02, HA03

ICAO TI / IATA DGR · Table A

Class
1.1D
Emergency response code
1L
ADR 2025 (UNECE) · RID / ADN / IMDG / ICAO listings via BAM

Required transport equipment

A pair of protective gloves
Eye protection
For each vehicle, a wheel chock
Portable lighting apparatus
Two self-standing warning signs
Warning vest
ADR 2025 (UNECE)

ADR 2025 · Table A

UN 0027
3a Class 1
3b Classification code 1.1D
4 Packing group
6 Special provisions
7a Limited quantities 0
7b Excepted quantities E0
8 Packing instructions P113
9a Special packing provisions PP50
9b Mixed packing provisions MP20MP24
10 Portable tank instructions
11 Portable tank special provisions
12 Tank code
13 Tank special provisions
14 Tank vehicle
15 Transport category 1
15 Tunnel restriction B1000C
20 Hazard ID (HIN)
ADR 2025 (UNECE)

ADR Packaging guide

Inner packaging
Outer packaging
4A4B4NBoxes steel aluminium other metal
Max per inner Max gross mass · Packing group
4C14C24DBoxes natural wood, ordinary natural wood, sift-proof walls plywood
Max per inner Max gross mass · Packing group
4F4G4H2Boxes reconstituted wood fibreboard plastics, solid
Max per inner Max gross mass · Packing group
4A4B4NBoxes steel aluminium other metal
Max per inner Max gross mass · Packing group
4C14C24DBoxes natural wood, ordinary natural wood, sift-proof walls plywood
Max per inner Max gross mass · Packing group
4F4G4H2Boxes reconstituted wood fibreboard plastics, solid
Max per inner Max gross mass · Packing group
1A11A21B11B21N11N21DDrums steel aluminium other metal plywood
Max per inner Max gross mass · Packing group
1GDrums fibre
Max per inner Max gross mass · Packing group
1H11H2Drums plastics
Max per inner Max gross mass · Packing group
1A11A21B11B21N11N21DDrums steel aluminium other metal plywood
Max per inner Max gross mass · Packing group
1GDrums fibre
Max per inner Max gross mass · Packing group
1H11H2Drums plastics
Max per inner Max gross mass · Packing group

Informational only — based on ADR 2025. Always verify against the original official source before carriage.

ADR Exemptions & reliefs

Limited Quantities (3.4)

Not eligible for Limited Quantity exemption.

Excepted Quantities (3.5)

Not eligible for Excepted Quantity exemption.

Transport-category points (1.1.3.6)1
Multiplier: × 50 · Limits 20

Informational only — based on ADR 2025. Always verify against the original official source before carriage.

Classification code 1.1D
Division 1.1: Substances and articles which have a mass explosion hazardCompatibility Group D: Secondary detonating explosive substance or black powder or article containing a secondary detonating explosive substance...
Transport category 1
Max Total Quantity per Transport Unit: 20 kg/LMultiplication Factor: 50Substances of Packing Group I... Class 1: 1.1B... (Factor 50)

1.1.3.6.4 Calculation: Where dangerous goods of different transport categories are carried in the same transport unit, the sum of:

  • The quantity of substances and articles of transport category 1 multiplied by 50;
  • The quantity of substances and articles of transport category 1 referred to in Note a to the table in 1.1.3.6.3 multiplied by 20;
  • The quantity of substances and articles of transport category 2 multiplied by 3; and
  • The quantity of substances and articles of transport category 3;
shall not exceed 1000.

Tunnel restriction B1000C
Carriage where the total net explosive mass per transport unit - exceeds 1000 kg: Passage forbidden through tunnels of category B, C, D and E; - does not exceed 1000 kg: Passage forbidden through tunnels of category C, D and E
Limited quantities 0
Not permitted as Limited Quantity.
Excepted quantities E0
Not permitted as Excepted Quantity.
Packing instructions 1
P113

The following packagings are authorized, provided the general packing provisions of 4.1.1, 4.1.3 and special packing provisions of 4.1.5 are met:

Additional requirement: The packaging shall be sift-proof.

Special packing provisions: PP49 For UN Nos. 0094 and 0305, no more than 50 g of substance shall be packed in an inner packaging. PP50 For UN No. 0027, inner packagings are not necessary when drums are used as outer packagings. PP51 For UN No. 0028, paper kraft or waxed paper sheets may be used as inner packagings.

P113 PACKING INSTRUCTION P113
Inner packagingsIntermediate packagingsOuter packagings
Bags paper plastics textile, rubberized Receptacles fibreboard metal plastics woodNot necessaryBoxes steel (4A) aluminium (4B) other metal (4N) natural wood, ordinary (4C1) natural wood, sift-proof walls (4C2) plywood (4D) reconstituted wood (4F) fibreboard (4G) plastics, solid (4H2)
Drums steel (1A1, 1A2) aluminium (1B1, 1B2) other metal (1N1, 1N2) plywood (1D) fibre (1G) plastics (1H1, 1H2)
Special packing provisions 1
PP50
For UN Nos. 0160, 0161 and 0508, inner packagings are not necessary if drums are used as outer packagings.
Mixed packing provisions 2
MP20
May be packed together with substances covered by the same UN number. Shall not be packed together with goods of Class 1 having different UN numbers, except if provided for by special provision MP 24. Shall not be packed together with goods of other classes or with goods which are not subject to the requirements of ADR.
MP24

May be packed together with goods with the UN numbers shown in the table below, under the following conditions:

3214Permanganates, inorganic, aqueous solution, n.o.s.5.1O1IIWater
3216Persulphates, inorganic, aqueous solution, n.o.s.5.1O1IIIWetting solution
3218Nitrates, inorganic, aqueous solution, n.o.s.5.1O1II/IIIWater
3219Nitrites, inorganic, aqueous solution, n.o.s.5.1O1II/IIIWater
3264Cupric chlorideaqueous solution, slightly corrosive8C1IIIWater
3264Hydroxylamine sulphate25 % aqueous solution8C1IIIWater
3264Phosphorous acidaqueous solution8C1IIIWater
UN No.Proper shipping name or technical nameDescriptionClassClassifi-cation CodePacking groupStandard liquid
3.1.23.1.22.22.22.1.1.3
-1(2a)(2b)(3a)(3b)-4-5
3264Corrosive liquid, acidic, inorganic, n.o.s.flashpoint more than 60 °C8C1I/II/IIIRule for collective entries; not applicable to mixtures having components of UN Nos.: 1830, 1832, 1906 and 2308
3265Methoxyacetic acid8C3In-Butyl acetate/ n-butyl acetate-saturated wetting solution
3265Allyl succinic acid anhydride8C3IIn-Butyl acetate/ n-butyl acetate-saturated wetting solution
3265Dithioglycolic acid8C3IIn-Butyl acetate/ n-butyl acetate-saturated wetting solution
3265Butyl phosphatemixture of mono- and di-butyl phosphate8C3IIIWetting solution
3265Caprylic acid8C3IIIn-Butyl acetate/ n-butyl acetate-saturated wetting solution
3265Isovaleric acid8C3IIIn-Butyl acetate/ n-butyl acetate-saturated wetting solution
3265Pelargonic acid8C3IIIn-Butyl acetate/ n-butyl acetate-saturated wetting solution
3265Pyruvic acid8C3IIIn-Butyl acetate/ n-butyl acetate-saturated wetting solution
3265Valeric acid8C3IIIAcetic acid
3265Corrosive liquid, acidic, organic, n.o.s.flashpoint more than 60 °C8C3I/II/IIIRule for collective entries
3266Sodium hydrosulphideaqueous solution8C5IIAcetic acid
3266Sodium sulphideaqueous solution, slightly corrosive8C5IIIAcetic acid
3266Corrosive liquid, basic, inorganic, n.o.s.flashpoint more than 60 °C8C5I/II/IIIRule for collective entries
32672,2'-(Butylimino)-bisethanol8C7IIMixture of hydrocarbons and wetting solution
Carriage — packages 2
V2

(1) Packages shall only be loaded on to EX/II or EX/III vehicles which satisfy the relevant requirements of Part 9. The choice of vehicle depends on the quantity to be carried, which is limited per transport unit in accordance with the provisions concerning loading (see 7.5.5.2). Where a transport unit consists of an EX/II vehicle and an EX/III vehicle, both carrying explosive substances or articles, the quantity limit of 7.5.5.2.1 applicable for an EX/II transport unit applies for the entire transport unit.

(2) Trailers, except semi-trailers, which satisfy the requirements for EX/II or EX/III vehicles may be drawn by motor vehicles which do not satisfy those requirements.

For carriage in containers, see also 7.1.3 to 7.1.6.

Where substances or articles of Class 1 in quantities requiring a transport unit made up of EX/III vehicle(s) are being carried in containers to or from harbour areas, rail terminals or airports of arrival or departure as part of a multimodal journey, a transport unit made up of EX/II vehicle(s) may be used instead, provided that the containers being carried comply with the appropriate requirements of the IMDG Code, the RID or the ICAO Technical Instructions.

V3
For free-flowing powdery substances and for fireworks the floor of a container shall have a non-metallic surface or covering.
Carriage — loading, unloading & handling 3
CV1
-1 The following operations are prohibited: (a) Loading or unloading goods in a public place in a built-up area without special permission from the competent authorities; (b) Loading or unloading goods in a public place elsewhere than in a built-up area without prior notice thereof having been given to the competent authorities, unless these operations are urgently necessary for reasons of safety. -2 If, for any reason, handling operations have to be carried out in a public place, then substances and articles of different kinds shall be separated according to the labels.
CV2
-1 Before loading, the loading surface of the vehicle or container shall be thoroughly cleaned. -2 The use of fire or naked flame shall be prohibited on vehicles and containers carrying goods, in their vicinity and during the loading and unloading of these goods.
CV3
See 7.5.5.2.
Carriage — operation 1
S1
CHAPTER 8.5 ADDITIONAL REQUIREMENTS RELATING TO PARTICULAR CLASSES OR SUBSTANCES In addition to the requirements of Chapters 8.1 to 8.4, when reference is made to them in Column (19) of Table A of Chapter 3.2, the following requirements shall apply to the carriage of the substances or articles concerned. In the event of conflict with the requirements of Chapters 8.1 to 8.4, the requirements of this Chapter shall take precedence. S1: Requirements concerning the carriage of explosive substances and articles (Class 1) (1) Special training of drivers If, according to other regulations applicable in the country of a Contracting Party, a driver has followed equivalent training under a different regime or for a different purpose, covering the subjects defined in 8.2.2.3.4, the specialization training course may be totally or partially dispensed with. (2) Approved official If the national regulations so provide, the competent authority of a country contracting party to ADR may require an approved official to be carried in the vehicle at the carrier's expense. (3) Prohibition of smoking, fire and naked flame Smoking, the use of fire or of naked flames shall be prohibited on vehicles carrying substances and articles of Class 1, in their vicinity and during the loading and unloading of these substances and articles. This prohibition of smoking is also applicable to the use of electronic cigarettes and similar devices. (4) Places of loading and unloading   (a) Loading or unloading of substances and articles of Class 1 shall not take place in a public place in a built-up area without special permission from the competent authorities;   (b) Loading or unloading of substances and articles of Class 1 in a public space elsewhere than in a built-up area without prior notice thereof having been given to the competent authorities shall be prohibited, unless operations are urgently necessary for reasons of safety;   (c) If, for any reason, handling operations have to be carried out in a public place, then substances and articles of different kinds shall be separated according to the labels;   (d) When vehicles carrying substances and articles of Class 1 are obliged to stop for loading or unloading operations in a public place, a distance of at least 50 m shall be maintained between the stationary vehicles. This distance shall not apply to vehicles belonging to the same transport unit. (5) Convoys   (a) When vehicles carrying substances and articles of Class 1 travel in convoy, a distance of not less than 50 m shall be maintained between each transport unit and the next;   (b) The competent authority may lay down rules for the order or composition of convoys.(6) Supervision of vehicles The requirements of Chapter 8.4 shall be applicable only when substances and articles of Class 1 having a total net mass of explosive substance above the limits set below are carried in a vehicle:
Division 1.1:0 kg
Division 1.2:0 kg
Division 1.3, compatibility group C:0 kg
Division 1.3, other than compatibility group C:50 kg
Division 1.4, other than those listed below:50 kg
Division 1.5:0 kg
Division 1.6:50 kg
Substances and articles of Division 1.4 belonging to UN Nos. 0104, 0237,0255,
0267, 0289, 0361, 0365, 0366, 0440, 0441, 0455, 0456, 0500, 0512 and 0513:0 kg

For mixed loads the lowest limit applicable to any of the substances or articles carried shall be used for the load as a whole. In addition, these substances and articles, when subject to the provisions in 1.10.3, shall be supervised in accordance with the security plan in 1.10.3.2 at all times to prevent any malicious act and to alert the driver and the competent authorities in the event of loss or fire. Empty uncleaned packagings are exempted. (7) Locking of vehicles Doors and rigid covers in the load compartments of EX/II vehicles and all openings in the load compartments of EX/III vehicles carrying substances and articles of Class 1 shall be locked during transport, except for the periods of loading and unloading. S2: Additional requirements concerning the carriage of flammable liquids or gases (1) Portable lighting apparatus The load compartment of closed vehicles carrying liquids having a flash-point of not more than 60 °C or flammable substances or articles of Class 2, shall not be entered by persons carrying portable lighting apparatus other than those so designed and constructed that they cannot ignite any flammable vapours or gases which may have penetrated into the interior of the vehicle. (2) Operation of combustion heaters during loading or unloading The operation of combustion heaters of vehicles of type FL (see Part 9) is forbidden during loading and unloading and at loading sites. (3) Precautions against electrostatic charges In the case of vehicles of type FL (see Part 9), a good electrical connection from the vehicle chassis to earth shall be established before tanks are filled or emptied. In addition, the rate of filling shall be limited. S3: Special provisions concerning the carriage of infectious substances The requirements of the table columns (2), (3) and (5) in 8.1.4.1 and the requirements in 8.3.4 shall not apply. S4: See 7.1.7. NOTE: This special provision S4 does not apply to substances referred to in 3.1.2.6 when substances are stabilized by the addition of chemical inhibitors such that the SADT is greater than 50 °C. In this case, temperature control may be required under conditions of carriage where the temperature may exceed 55 °C. S5: Special provisions common to the carriage of radioactive material of Class 7 in excepted packages (UN Nos. 2908, 2909, 2910 and 2911) only The requirements of the instructions in writing of 8.1.2.1 (b) and of 8.2.1, 8.3.1 and 8.3.4 shall not apply.

Source

UNECE — ADR 2025, the European Agreement concerning the International Carriage of Dangerous Goods by Road (Annex A, Table A) unece.org ↗
BAM Dangerous Goods Dataservice — RID / ADN / IMDG / ICAO listings (class, packing group and limited quantities per mode; no full text)

Regulatory text is the authoritative ADR 2025 text, shown as published — not translated. Always verify against the current official edition before carriage.

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